Nonisothermal oxidation behavior of Zircaloy-4 in steam.

The Influence of Hydrogen on the Deformation Behavior of Zircaloy-4

The deformation behavior of Zr-based cladding forms a basis for fuel behavior codes and affects failure criteria; as such, it is critical to reactor safety. The present study examines the influence of hydrogen on the uniaxial deformation behavior of hydrided cold worked and stressrelieved Zircaloy-4 plate material. Specimens of various orientations (i.e., stress axis aligned with the rolling di...

Mechanism of anodic oxide film formation on zircaloy-2, zircaloy-4, titanium and niobium (Radio tracer technique)

The kinetics of anodic oxidation of zircaloy-2, zircaloy-4, titanium and niobium have been studied in 0.1M sodium methoxide without and with addition of a millimole of sodium phosphate at a constant current density of 8mA.cm-2 and at room temperature (300 K). the addition of phosphate ions found to improve the kinetics of film formation. This trend and mechanism of anodic oxide film growth is c...

Preferential Field Evaporation during Atom Probe Analysis of Zircaloy-4

Kinetics of Ethanol Oxidation in High-Pressure Steam*

Ethanol oxidation rate in high pressure steam at the pressure of 10 MPa in the temperature ranging from 430 to 490 °C was studied with the fuel equivalence ratio of 0.4. On the assumption that the reaction order is first order, the reaction rate parameters obtained in the experiments are 10 ± 0.4 s for the pre-exponential factor and 166.5 ± 6.1 kJ·mol for the activation energy. This ethanol oxi...

determination of olanzapine and thiourea using electrodes modified by dna and film of copper-cobalt hexacyanoferrate & investigation of electro-oxidation of some catechol derivatives in the presence of 4-phenylsemicarbazid

چکیده هدف از این کار بررسی الکترواکسیداسیون کتکول و مشتقات آن در حضور 4-فنیل سمی کاربامازید بوده است اکسیداسیون کتکولها ترکیبات نا پایدار کینونها را تولید می کنند که این ترکیبات می تواند در واکنش مایکل بعنوان پذیرنده نوکلئوفیل عمل نمایند. در ادامه اکسایش کتکولهای (a-c1) را درحضور 4-فنیل سمی کاربامازید در محلول آب/استونیتریل (90/10)بوسیله ولتامتری چرخه ای و کولن متری در پتانسیل ثابت مورد بررسی ...